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Programs are mostly not possible to backup, because they often need registry keys to work. You can fiddle with it, but 95% chance you can't.
You can best backup c:\documents and settings\yourmumsusername.
You will have all her personal stuff backed up.
If she uses Outlook express, then it would be wise to backup her addressbook (search for *.wab on her c: drive). And also make a backup of her account (options\accounts\export).
May i ask why u need to do this ? If it's only to repair XP, then it is better to do a repair install.
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