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Check under the "Advanced" section for the "OnChip SATA Boot Rom". Make sure that it is set to "Enabled". Then under the "Boot" options you will see 3 boot options. Highlight the hard drive listing (this should be the IDE one that is booting), and change it to the SATA drive listing. Save, and exit.
The problem is that boards SATA controller is a seperate chip, and not part of the chipset. As such it will always default boot to any internal drives handled by the chipset first. If you follow the above this should change it to boot to the SATA drive.
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