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(answer to #1, #2, #3) Almost all gear operates at one of two levels: +4dBu or -10dBV. (The difference between those two levels, contrary to what you might think, is not 14dB. It's only 11.79dB. The mathematics behind this are beyond the scope of this post.) +4 usually means "professional" and -10 usually means "consumer". However, the Audigy is set up for +4 operation.
(#4) The last amplification stage on the soundcard is a line driver, which both sets the output level, and makes the output impedance appropriate for either another amplifier, or headphones. You do not want to bypass this amplifier.
(#5) The best way to check this is to hook up your amplifier to the sound card and to some speakers, and play some loud, clean music very quietly--rock music from the 80's is a good choice, because the levels in the music reach 0dBFS (full-signal, in other words) but the music itself doesn't sound horribly distorted, so you will be able to hear if your amplifier is distorting it. Make sure that the signal leaving your soundcard is full-strength; the only volume control that should be anywhere other than 100% should be in your amplifier.
If you hear distortion (which I highly doubt you will) you can connect a "gain" plugin in the kX DSP before the output of the soundcard, to turn the output signal down so it's not too much for your amplifier. If your amp can handle the higher level signal, it is much preferred that you leave the Audigy output level at full-strength, so as to get the best signal-to-noise ratio.
It is most likely that you will not hear any distortion at all, until the amplifier itself becomes voltage-limited and starts to clip. This would happen when it is very, very loud, most likely. It is a Good Idea to check for distortion when it's fairly quiet; if distortion is present at higher power levels, you can blow out the tweeters on your nice Hi-Fi speakers.
Best of luck! :-)
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